全文获取类型
收费全文 | 291篇 |
免费 | 2篇 |
国内免费 | 6篇 |
专业分类
安全科学 | 3篇 |
废物处理 | 8篇 |
环保管理 | 27篇 |
综合类 | 45篇 |
基础理论 | 64篇 |
环境理论 | 1篇 |
污染及防治 | 109篇 |
评价与监测 | 26篇 |
社会与环境 | 16篇 |
出版年
2023年 | 2篇 |
2022年 | 10篇 |
2021年 | 21篇 |
2020年 | 6篇 |
2019年 | 4篇 |
2018年 | 7篇 |
2017年 | 11篇 |
2016年 | 23篇 |
2015年 | 10篇 |
2014年 | 9篇 |
2013年 | 31篇 |
2012年 | 12篇 |
2011年 | 27篇 |
2010年 | 14篇 |
2009年 | 19篇 |
2008年 | 9篇 |
2007年 | 16篇 |
2006年 | 13篇 |
2005年 | 10篇 |
2004年 | 13篇 |
2003年 | 4篇 |
2002年 | 7篇 |
2001年 | 3篇 |
2000年 | 5篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1981年 | 2篇 |
排序方式: 共有299条查询结果,搜索用时 375 毫秒
91.
Polar organic chemical integrative sampler (POCIS): application for monitoring organic micropollutants in wastewater effluent and surface water 总被引:1,自引:0,他引:1
Miège C Budzinski H Jacquet R Soulier C Pelte T Coquery M 《Journal of environmental monitoring : JEM》2012,14(2):626-635
In this paper, we discuss the advantages and drawbacks of POCIS (Polar Organic Chemical Integrative Sampler) for the evaluation of river water quality downstream of wastewater treatment plants. POCIS proved well adapted to sampling alkylphenols and several pharmaceuticals. Concentration factors and the decrease in limits of quantification, compared to grab water sample analyses, were significant except for hormones, β-blockers and bronchodilators. Promising preliminary results obtained in situ on deuterated atenolol used as a performance reference compound need to be confirmed in-lab. This work confirms that POCIS is a valuable tool for monitoring hydrophilic organic molecules in river and wastewaters. 相似文献
92.
Heavy metal and trace elements in riparian vegetation and macrophytes associated with lacustrine systems in Northern Patagonia Andean Range 总被引:1,自引:0,他引:1
Andrea Juárez María A. Arribére Marina Arcagni Natalia Williams Andrea Rizzo Sergio Ribeiro Guevara 《Environmental science and pollution research international》2016,23(18):17995-18009
Vegetation associated with lacustrine systems in Northern Patagonia was studied for heavy metal and trace element contents, regarding their elemental contribution to these aquatic ecosystems. The research focused on native species and exotic vascular plant Salix spp. potential for absorbing heavy metals and trace elements. The native species studied were riparian Amomyrtus luma, Austrocedrus chilensis, Chusquea culeou, Desfontainia fulgens, Escallonia rubra, Gaultheria mucronata, Lomatia hirsuta, Luma apiculata, Maytenus boaria, Myrceugenia exsucca, Nothofagus antarctica, Nothofagus dombeyi, Schinus patagonicus, and Weinmannia trichosperma, and macrophytes Hydrocotyle chamaemorus, Isöetes chubutiana, Galium sp., Myriophyllum quitense, Nitella sp. (algae), Potamogeton linguatus, Ranunculus sp., and Schoenoplectus californicus. Fresh leaves were analyzed as well as leaves decomposing within the aquatic bodies, collected from lakes Futalaufquen and Rivadavia (Los Alerces National Park), and lakes Moreno and Nahuel Huapi (Nahuel Huapi National Park). The elements studied were heavy metals Ag, As, Cd, Hg, and U, major elements Ca, K, and Fe, and trace elements Ba, Br, Co, Cr, Cs, Hf, Na, Rb, Se, Sr, and Zn. Geochemical tracers La and Sm were also determined to evaluate contamination of the biological tissues by geological particulate (sediment, soil, dust) and to implement concentration corrections. 相似文献
93.
The degradation of nonylphenol (NP) in aqueous solution with UV, H2O2/UV, and Fenton/photo-Fenton processes was studied. The efficacy of direct and hydrogen peroxide photolysis proved to be dependent on the pH value. The addition of H2O2 to UV treatment improved NP degradation. The application of UV photolysis and the H2O2/UV system at pH 7 resulted in low pseudo first-order rate constants at 10-4 sec-1. In the experiments at elevated pH values the pseudo-first order rate constants increased to 10-3 sec-1. The efficacy of the Fenton process was lower in comparison with UV and hydrogen peroxide photolysis. The addition of UV irradiation to the H2O2/Fe2+ system substantially improved NP degradation efficacy. In terms of performance, the photo-Fenton process was similar to the H2O2/UV process. The most favourable process for complete nonylphenol degradation considering both operational cost and treatment efficacy was H2O2/UV at pH 11 and 250 mol/L H2O2. 相似文献
94.
Bigliardi Ana Paula Fernandes Caroline Lopes Feijo Pinto Edlaine Acosta dos Santos Marina Garcia Edariane Menestrino Baisch Paulo Roberto Martins Soares Maria Cristina Flores Muccillo-Baisch Ana Luíza da Silva Júnior Flavio Manoel Rodrigues 《Environmental science and pollution research international》2021,28(2):1409-1416
Environmental Science and Pollution Research - Coal extraction and processing generate environmental contamination, which has several negative impacts on human health. Hematological and biochemical... 相似文献
95.
96.
Silva Neicí Cáceres Poetini Márcia Rósula Bianchini Matheus Chimelo Almeida Francielli Polet Dahle Mustafá Munir Mustafa Araujo Stífani Machado Bortolotto Vandreza Cardoso Musachio Elize Aparecida Santos Ramborger Bruna Piaia Novo Diogo La Rosa Roehrs Rafael Mesko Marcia Foster Prigol Marina Puntel Robson Luiz 《Environmental science and pollution research international》2021,28(14):17519-17531
Environmental Science and Pollution Research - Manganese (Mn) is an essential element that, in excess, seems to be involved in the development of different neurodegenerative conditions.... 相似文献
97.
NASRI Khouloud GREGOIRE Gwendoline MURAT Anne FIALLO Marina 《Environmental science and pollution research international》2021,28(7):8128-8139
Environmental Science and Pollution Research - Anthropocene mineral diversity is the result of the purification of metals naturally combined with other chemical elements in natural environment.... 相似文献
98.
Organosilicas with chemically immobilized 3-aminopropyl and Methyl Red-containing surface groups were prepared by sol-gel condensation of tetraethyl orthosilicate and (3-aminopropyl)triethoxysilane in the presence of dye as part of the mixed micelles or dye-containing silane as silica source. The hexagonally arranged mesoporous structure of synthesized materials was confirmed by low-temperature nitrogen adsorption-desorption, x-ray diffraction, and TEM studies. Chemical composition of MCM-41-type organosilicas was established by FT-IR spectroscopy and chemical analysis of surface layer. Sorption of Methyl Red by organosilicas was studied from diluted phosphate buffer solutions in dependence of medium pH, duration of contact, and equilibrium concentration of dye. It was found that effective removal of Methyl Red takes place at pH values within a range of 2.5?5. Kinetic curves of Methyl Red sorption on organosilicas were analyzed by the Lagergren, Ho-McKey, and Weber-Morris kinetic models. It was found that the pseudo-second-order model fits the kinetics of Methyl Red sorption on all synthesized materials and the intraparticle diffusion is not the only one mechanism controlling the rate of Methyl Red sorptive removal. The parameters of equilibrium sorption of Methyl Red on organosilicas of MCM-41 type were calculated using Langmuir, Freundlich, Redlich-Peterson, and Brunauer-Emmett-Teller models. Sorption of acid dyes with geometry similar or substantially different from Methyl Red on mesoporous silicas was studied from single and binary component mixtures in aqueous solutions with pH 4.8 and 5.5. It was found that selective sorption process is highly dependent on the structural characteristics and protolytic state of silica surface as well as acid dye. 相似文献
99.
Adrian Vallin Marina Dimitrova Ullasa Kodandaramaiah Sami Merilaita 《Behavioral ecology and sociobiology》2011,65(8):1629-1636
Eyespots (patterns of roughly concentric rings) are often thought to have an anti-predator function. Previous experiments
have lent support for the intimidation hypothesis by demonstrating a deterring effect of eyespots, but so far there is little
evidence for the deflective effect (direction of attacks toward less vital body parts). We studied predators’ responses towards
large and small eyespots and towards prey with no, one, or a pair of eyespots and if this response is influenced by whether
or not prey blend into background. In two experiments, we used artificial, triangular prey items and blue tits (Cyanistes caeruleus) as predators. In experiment 1, we found evidence for the deflective effect of small but not large eyespots, independent
of whether the prey was presented on a concealing or exposing background. In experiment 2, we found that predators avoided
the prey with a pair of small eyespots more than the prey without eyespots, but interestingly, we only found this deterring
effect on the concealing background. There was no difference in attacks between the prey with one large and two small or one
large and no eyespots. We conclude that deflective function may select for eyespots, and background may influence the deterring
function of eyespots. 相似文献
100.
Combined chemical treatment of pharmaceutical effluents from medical ointment production 总被引:2,自引:0,他引:2
Three wastewater samples from a pharmaceutical plant formulating medical ointments were subjected to lab-scale treatment by a Fenton-like system in combination with lime coagulation. All samples were plant pre-treated by adsorption/flocculation/filtration processes with utilization of bentonite, but the quality of effluents did not comply with the regulations for wastewater discharged to local sewerage. The optimization of Fenton-like oxidation demonstrated the highest process efficacy at H(2)O(2)/COD weight ratio of 2:1, H(2)O(2)/Fe(2+) molar ratio of 10:1 and 2h of treatment time. The fast pH decrease to acidic values approximately 3 during first min of oxidation for all effluents suggested that pH adjustment was unnecessary. Combination of Fe(III) precipitation and lime coagulation proved feasible to improve considerably COD and residual iron concentration reduction in pharmaceutical effluents. Additionally, considerable BOD(7) reduction and BOD(7)/COD ratio improvement of pharmaceutical wastewater samples was achieved by combined treatment. The application of Fenton-like oxidation with subsequent iron (III)/lime coagulation did not only enhance the quality of pharmaceutical effluents with different chemical characteristics and help to meet the requirements for wastewater discharged to sewage, but also improve the biodegradability of pharmaceutical effluents. 相似文献